Cool post, we need more people that know something about motorola 8 bit assembly language!
I am in no way capable of giving you even a decent crash course, I too am pretty much a beginner, starting off only using a subset of the language maybe two years ago now.
The only past experience I had was with PIC as well, and not even much assembly at that (I used JAL and some PIC asm). The learning curve of the motorola assembly is somewhat steep, but it is fruitful. The motorola cpu programming model is widely used in the automotive efi industry in different variants, as you well know, so knowledge is this area is valuable
Before you start rewriting/confirming the code you are going to need simulation. This wouldnt be necessary if you were pro, but thats not what this is about. Because there is no hope for any sort of full software simulation of the ECU code (some unknown external hardware and functions), you must rig up at least a semi-complete bench simulation.
The bench simulation provides a running code from which you can update and debug with the use of rom emulation and serial debugging tools (already provided with consult or Nistune).
The most difficult part of the ECU hardware simulation is the function of the crank angle sensor. Because our nissan CAS are complex units, outputting high resolution signals, the only feasible way to simulate this unit on the bench (aside from spinning an actual CAS with a motor) is to use a microcontroller.
The one I use is designed for the ka24e(de)/sr20de CAS and the information I used to build it was provided by a nice guy named Erich on the ECCS-TEC forums.
You can start analyzing the code before this, but before you do any real code reconfiguration your going to need to watch and confirm some ram bytes.
Here is the complete hd63b03ycp datasheet. Opcodes and the programming model is provided pages 156-161. Print this datasheet out and put in a good binder. This binder should also include as many hardware datasheets you can find for your ECU, and any references you may need (such as large easy to read binary/hex/decimal conversion chart).
http://www.hybridka.com/misc/hd63b03ycp.zip